GenetixBayEST. 2009
Glossary · Nutrients

Iron chelate

An iron chelate is iron bound to an organic molecule (EDTA, DTPA or EDDHA) that keeps it dissolved and available; each type holds up to a different pH.

Also written chelated ironFe chelateFe-EDTAFe-DTPAFe-EDDHAiron EDTA

EstablishedDraft: awaiting expert reviewUpdated

An iron chelate is ferric iron held in a ring-like organic molecule, the chelating agent, which stops it from forming insoluble hydroxides. The three common types are Fe-EDTA (about 13% Fe), Fe-DTPA (about 10-11% Fe) and Fe-EDDHA (about 6% Fe). They differ mainly in how high a pH they survive.

In practice

Fe-EDTA works well up to about pH 6.0-6.5, fine for most hydro but weak in high-pH soil or water. Fe-DTPA holds to about pH 7.0-7.5 and is the usual choice for coco and hydro. Fe-EDDHA stays effective to pH 9 or more and is used for alkaline soils; it stains solutions dark red. EDTA iron also breaks down in strong light, so opaque reservoirs help. Feeds typically target about 1-3 mg/L (ppm) Fe.

Don't confuse with

  • Iron sulfate: unchelated iron, precipitates quickly above pH 6.
  • Iron oxide or rust: insoluble and unavailable to roots.
  • Amino acid chelates: weaker, less stable bonding, different behaviour in solution.

Related terms

Sources

  1. HortScience. 2025. Iron chelates (Fe-EDTA, Fe-DTPA, Fe-EDDHA) in high-pH soilless media. HortScience 60(3):404. journals.ashs.org/view/journals/hortsci/60/3/article-p404.xm
  2. Sonneveld C, Voogt W. 2009. Plant Nutrition of Greenhouse Crops. Springer. doi.org/10.1007/978-90-481-2532-6
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