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Glossary · pH, EC and water

Free chlorine

Free chlorine is the disinfectant (hypochlorous acid and hypochlorite) added to many tap waters; it dissipates from standing or aerated water within about a day.

Also written chlorine (water treatment)residual chlorinehypochloritehypochlorous acidchlorinated water

EstablishedDraft: awaiting expert reviewUpdated

Free chlorine is the chlorine in water present as hypochlorous acid (HOCl) and hypochlorite ion (OCl⁻), the active forms produced when chlorine gas or sodium hypochlorite is added for disinfection. Drinking water usually carries a residual well under the 4 mg/L US limit. The balance between HOCl and OCl⁻ depends on pH; HOCl, the stronger disinfectant, dominates below about pH 7.5.

In practice

Free chlorine is volatile. Standing water in an open container loses much of it within 24 hours, faster with aeration or stirring. Carbon filters remove it efficiently, and RO pre-filters are designed to strip it to protect the membrane. Ascorbic acid also neutralises it.

Growers dechlorinate mainly to protect microbes in living soil, compost teas or beneficial reservoirs. Direct harm to cannabis at tap-water levels is not well documented. Some hydro growers deliberately add low doses of hypochlorite to sterile reservoirs; that is a separate, deliberate strategy that needs commitment.

Don't confuse with

  • Chloramine: chlorine bound to ammonia; stable, does not evaporate.
  • Chloride (Cl⁻): the plant micronutrient, harmless at normal levels.
  • Chlorine (nutrient): the element as a plant nutrient, a separate entry.

Related terms

Sources

  1. Water Quality Association. 2014. Chloramine fact sheet. wqa.org/wp-content/uploads/2022/09/2014_Chloramine.pdf
  2. USDA Forest Service. Vitamin C dechlorination. fs.usda.gov/t-d/pubs/html/05231301/05231301.html
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