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Glossary · Systems and media

Cation exchange capacity

Cation exchange capacity (CEC) is a medium's ability to hold positively charged nutrients such as calcium, magnesium and potassium on its surfaces and release them later.

Also written CECcation exchangeexchange capacitycation-exchange capacity

EstablishedDraft: awaiting expert reviewUpdated

Cation exchange capacity is the total amount of exchangeable positive ions (cations) that a medium can hold on negatively charged sites on clay, organic matter and organic fibres. Held cations, such as Ca²⁺, Mg²⁺, K⁺, NH₄⁺ and Na⁺, are not washed straight out; they swap with others in the soil solution, giving a nutrient reserve and buffering against sudden change.

In practice

High-CEC media (clay soils, compost-rich soil, peat, vermiculite) are forgiving: they hold nutrients between feeds and resist pH swings. Low-CEC media (rockwool, perlite, clay pebbles, sand) hold almost nothing, so the plant sees exactly what is in the solution. Coco sits in between and has a characteristic preference: its sites load with potassium and sodium during processing and tend to grab calcium and magnesium from feed, which is why coco is buffered with calcium before use.

Units and formula

CEC is measured in centimoles of charge per kilogram (cmol(+)/kg), equivalent to milliequivalents per 100 g (meq/100 g). Sandy soils are often under 10; clay- and humus-rich soils 20-40 or more.

Don't confuse with

  • Buffering (pH): resistance to pH change; related but not the same quantity.
  • EC: dissolved salts in solution; CEC is nutrients held on solids.

Related terms

Sources

  1. Brady NC, Weil RR, 2017. The Nature and Properties of Soils, 15th ed. Pearson..
  2. Raviv M, Lieth JH, Bar-Tal A (eds), 2019. Soilless Culture: Theory and Practice, 2nd ed. Elsevier. doi.org/10.1016/C2015-0-01807-5
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